Citric Acid 25% Solution

Category : Acids

$19.93
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Citric Acid 25% Solution

$19.93

Quick Answer

What is Citric Acid 25% Solution used for, and what should buyers verify before ordering?

Citric Acid 25% Solution is supplied at 24.5-25.5% in Technical grade with UN 1760, DOT Class 8 . Buyers should confirm pack size, grade, SDS, COA needs, and freight requirements before purchase.

  • Assay: 24.5-25.5%
  • Grade: Technical
  • UN number: UN 1760
  • DOT class: 8
  • Documents: SDS and lot-specific COA support
  • Shipping: UPS for small packs; LTL/FTL for pails, drums, totes, and bulk orders

Commercial Fulfillment Snapshot

Buy Citric Acid 25% Solution with faster decisions and fewer back-and-forth emails.

Ships from Taylor, Texas. In-stock orders placed before 1:00 PM CT (Mon-Thu) and before 12:00 PM CT (Fri) typically ship within 1-2 business days. Order online 24/7.

Technical Documents

Live, always-current docs · lot-specific COA issued per shipment batch.

Who Buys This
  • Food & beverage processors
  • Pharmaceutical manufacturers
  • Industrial cleaning companies
  • Cosmetic & personal care makers
  • Nutritional supplement producers
Purity / Grade Guide
  • Industrial & lab applications
  • Verified purity, COA included
  • Suitable for commercial use
  • 25% concentration for easy handling
Pack Sizes
  • 1 Quart: lab & small jobs
  • 1 Gallon: shop & maintenance
  • 5 Gallon: production & regular use
  • 15 Gallon: mid-volume operations
  • 55 Gallon: bulk drum
  • 275 Gallon: high-volume tote
  • 330 Gallon: max-volume tote
SDS / COA / TDS
  • SDS
  • COA
  • Non-regulated ground shipment
  • Warning label Class 8
Small Packs: UPS Ground nationwide for pints, quarts, and gallons.
LTL / FTL: ABF, SEFL, Saia, XPO, and partner carriers for pails, drums, totes, and full truckloads.
Support: Email or call for freight options, hazardous-material routing, and lead-time confirmation.

Product Overview

Citric Acid 25% Solution is a premium, pre-diluted aqueous formulation of citric acid designed specifically for direct industrial operations. This high-purity liquid solution completely eliminates the intensive operational steps required to dissolve solid crystalline citric acid, thereby preventing hazardous dust generation and ensuring immediate homogeneity within your chemical process streams. As an organic acid, citric acid serves as an exceptionally effective chelating agent, pH adjuster, and chemical intermediate across a wide spectrum of manufacturing sectors. Alliance Chemical distributes this precise formulation in multiple packaging configurations, ranging from convenient quarts to heavy-duty industrial drums and totes, ensuring we meet your facilities' specific procurement and handling requirements seamlessly.

The raw material utilized to manufacture this 25% aqueous solution has a molecular structure represented by the chemical formula C6H8O7, a molecular weight of 192.12, and is identified by CAS number 77-92-9. Providing a highly consistent 25% concentration allows facilities to completely bypass manual hydration and dilution processes, dramatically reducing labor costs while eliminating critical mixing and calculation errors. This pre-formulated liquid concentration is ideal for automated chemical dosing systems where precise volumetric control and predictable chemical behavior are required. For comprehensive quality assurance, a dedicated Certificate of Analysis (COA) is available upon request for every single manufacturing lot.

Why This Grade

Although no specific regulatory grade is defined — the grade is not applicable for this raw material stream — this industrial-strength 25% concentration offers significant processing and safety advantages over dry anhydrous alternatives. Handling dry citric acid crystals introduces substantial airborne dust hazards, which requires expensive air filtration systems and poses inhalation risks to floor operators. Furthermore, dry crystals are highly prone to caking and solidifying in humid storage environments, which complicates bulk handling. A stabilized liquid solution ensures a consistent density and viscosity, facilitating highly predictable, uninterrupted flow rates through industrial chemical dosing pumps without the risk of crystallization or line clogging.

Utilizing an incorrect chemical concentration or attempting to perform manual on-site dilution introduces severe failure modes in industrial processes. An under-concentration below the required 25% threshold can lead to inadequate pH adjustment, which fails to neutralize alkaline process streams and can ruin sensitive chemical batches. Conversely, attempting to handle over-concentrated solutions can lead to localized precipitation, forming solid citric acid crystals that block piping, damage pumps, and cause expensive unscheduled plant downtime. By relying on our standardized 25% solution, facilities maintain tight operational tolerances. Explore our acids collection to review alternative chemical options for your plant.

Chemical Profile

CAS Number
77-92-9
Chemical Formula
C6H8O7
Molecular Weight
192.12 g/mol
Boiling Point
Decomposes (NTP, 1992) °C
Melting Point
307 °F (anhydrous) (NTP, 1992)
Flash Point
100 °C
Specific Gravity
1.54 at 68 °F (USCG, 1999) - Denser than water; will sink
Appearance
Citric acid appears as colorless, odorless crystals with an acid taste. Denser than water. (USCG, 1999)
Solubility
greater than or equal to 100 mg/mL at 72 °F (NTP, 1992)
UN Number
UN1760
Hazard Class
Class 8
Packing Group
III
Proper Shipping Name
Corrosive liquid n.o.s. (Citric acid)
GHS Signal Word
WARNING

Values sourced from Alliance Chemical's canonical chemistry registry. Certificate of Analysis (COA) per lot.

Industrial Applications

  • Metal Surface Cleaning: Used as a mild chelating agent to remove rust, scale, and metal oxides from industrial heat exchangers, piping networks, and boiler systems without damaging base metals.
  • Industrial Water Treatment: Serves as a reliable acidulant to adjust pH levels in industrial wastewater streams, neutralizing alkaline effluents before safe discharge into municipal systems.
  • Textile and Dye Processing: Applied in industrial textile manufacturing to precisely regulate pH levels in dye baths, ensuring uniform color fixation on both synthetic and natural fibers.
  • Industrial Detergent Formulations: Integrated into commercial cleaning compounds to sequester calcium and magnesium ions, effectively preventing hard water scale accumulation on mechanical components.
  • Construction Chemistry: Utilized as an effective concrete set retarder in specialty cement formulations, extending the working time and improving the workability of high-performance architectural concrete mixes.

Hazmat & Shipping

Citric Acid 25% Solution is classified as a regulated hazardous material for transportation under Department of Transportation regulations. It is shipped under the United Nations identification number UN1760, hazard class 8 (Corrosive), and packing group III. The proper shipping name required for transit documents is Corrosive liquid n.o.s. (Citric acid). The designated GHS signal word for this material is WARNING. Because it is classified as a corrosive liquid, specialized transport protocols must be strictly followed, and Alliance Chemical ensures that all packaging and logistics comply fully with domestic and international hazmat regulations.

In strict compliance with GHS safety guidelines, handling this solution requires appropriate personal protective equipment (PPE) to protect operators. This liquid formulation carries the GHS hazard statements H319 (Causes serious eye irritation) and H335 (May cause respiratory irritation); there are no GHS pictograms associated with this specific hazard classification in the canonical data. Operators must wear chemical-resistant gloves, protective clothing, and eye protection as dictated by precautionary statement P280. If accidental exposure occurs, refer immediately to the precautionary statements such as P305+P351+P338 for eye contact. A detailed Safety Data Sheet (SDS) is provided with every order to support your facility's safety and regulatory compliance programs.

Handling & Storage

Proper storage of Citric Acid 25% Solution is necessary to maintain product stability and prevent equipment damage. Keep the chemical stored in a cool, dry, well-ventilated warehouse, ideally maintained within a temperature range of 50°F to 85°F to prevent any localized freezing or evaporation. Suitable storage container materials include high-density polyethylene (HDPE), polypropylene, and fiberglass-reinforced plastic (FRP). Avoid storing this acidic solution in carbon steel, copper, or aluminum vessels, as the corrosive nature of the acid can react with these metals to generate hydrogen gas. Keep containers tightly closed when not in use, and store away from incompatible materials such as strong bases, strong oxidizing agents, and metal nitrates.

Order & Documentation

Alliance Chemical is dedicated to providing complete transparency and technical support for all your bulk and specialty chemical requirements. A comprehensive Safety Data Sheet (SDS) is provided with every order to ensure safe handling, and a certified Certificate of Analysis (COA) is readily available upon request to verify the physical properties and purity of your specific chemical batch. You can explore our extensive selection of industrial products in our water treatment industry solutions portal. To secure dependable chemical supplies for your operations, please Request a Quote for bulk pricing or Download the SDS directly from our site today.

Why Buy from Alliance Chemical

Since 1997, Alliance Chemical has supplied premium industrial chemicals from Taylor, Texas under CAGE Code 1LT50, with a COA and SDS included on every order. For industrial use only.

Property Value
Molecular Weight 192.13
Formula C6H8O7
Assay 24.5-25.5%
Grade Technical
Form Liquid
Solubility Soluble in water
Appearance Clear, colorless liquid
Melting Point 153
Boiling Point 152
Specific Gravity 1.05
Industry Food and Beverage, Pharmaceutical, Industrial Cleaning, Health and Nutrition, Personal Care

Frequently Asked Questions About Citric Acid 25% Solution

What is Citric Acid 25% Solution and what is its chemical formula?
Citric Acid 25% Solution is a chemical compound with the molecular formula C6H8O7, registered under CAS Number 77-92-9 by the Chemical Abstracts Service (PubChem), with a molecular weight of 192.12 g/mol. Alliance Chemical supplies Citric Acid 25% Solution in Technical grade for laboratory, industrial, and commercial applications.
What are the physical properties of Citric Acid 25% Solution?
According to the NIOSH Pocket Guide to Chemical Hazards, Citric Acid 25% Solution has a clear, colorless liquid appearance. It has a melting point of 153°C (307.4°F)°C, a boiling point of 152°C (305.6°F)°C. Solubility: Soluble in water, alcohol, and ether.
What grade and purity of Citric Acid 25% Solution does Alliance Chemical offer?
Alliance Chemical offers Citric Acid 25% Solution in Technical grade with a purity assay of 25%. Every lot ships with a Certificate of Analysis (COA) and Safety Data Sheet (SDS) prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and GHS Revision 7. Download SDS.
What are common industrial applications of Citric Acid 25% Solution?
Citric Acid 25% Solution has applications in laboratory research, manufacturing, and industrial processing.Alliance Chemical provides the documentation and quality certifications required for use in regulated environments.
What PPE is required when handling Citric Acid 25% Solution?
OSHA-mandated PPE per 29 CFR 1910.132-138:Chemical-resistant gloves (20+ mil neoprene or PVC), full face shield over safety goggles (ANSI Z87.1), acid-resistant apron or chemical suit, closed-toe chemical-resistant footwear. Emergency eyewash station and safety shower must be accessible within 10 seconds per ANSI Z358.1. Consult the SDS available from Alliance Chemical for complete PPE requirements.
What are the storage requirements for Citric Acid 25% Solution?
Store perOSHA 29 CFR 1910.1450: Dedicated corrosives cabinet with secondary containment (110% volume per EPA 40 CFR 264.175). Temperature range:15-25°C. Segregate from:bases, reactive metals, organic materials. Maximum storage:2-3 years unopened.
What is the emergency spill procedure for Citric Acid 25% Solution?
Emergency response per EPA SPCC (40 CFR 112) and OSHA 29 CFR 1910.120: (1) Alert personnel, evacuate area to 50 feet. (2) Eliminate ignition sources if flammable. (3) Don PPE per SDS Section 8. (4) Stop leak if safe; use emergency shutoffs. (5) Contain with non-combustible absorbent materials, dike with sand/earth. (6)Carefully neutralize with sodium bicarbonate (5-10% solution), monitor exothermic reaction. (7) Collect in DOT-approved containers, label as hazardous waste. Check 40 CFR 302.4 for Reportable Quantity. Emergency: Chemtel 1-800-255-3924 (24/7). Non-emergency: Alliance Chemical 512-365-6838.
What is the DOT shipping classification for Citric Acid 25% Solution?
DOT Classification per 49 CFR 172.101:UNUN1760, Hazard Class8 (Corrosive), Packing GroupII/III. Requires: Hazmat shipping papers (49 CFR 172.200), UN specification packaging (49 CFR 173), hazmat labels (172.400). Alliance Chemical ships all orders in DOT-compliant packaging with proper documentation.
How must Citric Acid 25% Solution waste be disposed?
Disposal per RCRA (40 CFR 261-265):Characteristic waste D002 (Corrosive, pH ≤2 or ≥12.5). Generator requirements: EPA ID number required if >100 kg/month (40 CFR 262.12). Use EPA-permitted Treatment, Storage, Disposal Facility (TSDF). Never discharge to sewer without POTW written approval (40 CFR 403). Container disposal: Triple rinse (40 CFR 261.7), offer for reconditioning/recycling. State regulations may be more stringent — check with your local environmental agency. Consult the Alliance Chemical SDS for product-specific disposal guidance.
Does Alliance Chemical provide an SDS and COA for Citric Acid 25% Solution?
Yes. Alliance Chemical provides a Safety Data Sheet (SDS) and Certificate of Analysis (COA) for every lot of Citric Acid 25% Solution. The SDS is prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and the Globally Harmonized System (GHS) Revision 7, covering all 16 required sections including hazard identification, first aid measures, firefighting measures, handling and storage, exposure controls, and regulatory information. The SDS is available for download directly from this product page. COAs are available upon request by contacting Alliance Chemical at 512-365-6838.